Product ID:TITANIUM TRICHLORIDE AA, TYPES C AND D
MSDS Date:11/01/1990
FSC:6810
NIIN:00N019048
MSDS Number: BLDRV

AKZO CHEMICALS INC

300 S RIVERSIDE
CHICAGO, IL 60606
US

Emergency Phone: 312-906-7500

Info Phone: 312-906-7500

Cage: 1F176

AKZO NOBEL CHEMICALS INC

CHICAGO, IL 60606-6613 US

Telephone: 800-828-792

Cage: 97854

TITANIUM ALUMINUM CHLORIDE;(TITANIUM TRICHLORIDE, ALUMINUM

CAS: 12003-13-3

Fraction By Weight: 100%

WATER TO ENTER WATERWAYS.

RTECS: 9999999ZZ

EQUIP MUST NOT BE USED UNTIL PROPERLY

RTECS: 9999999ZZ

DELAYED SEVERAL HOURS. PREVENT EXPOSURE.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:RECOM LIMITS: MFR RECOMS EXPOS LIMITS
BASED ON SIMILAR PRODS: HCL:5 PPM,C; TITANIUM DIOXIDE: PEL/TLV
10MG/M3; 5 RESP. MOISTURE LIBERATES TOX & CORR SUBSTANCES.
SKIN/EYE: CONTACT MAY RESULT IN SEVERE I RRIT/BURNS.
INHAL:POWDER/FUMES MAY PRDCE SEVERE BURNS OF UPPER RESP TRACT OR
LUNG INJURY & PULM EDEMA.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG DISEASES MAY BE
AGGRAVATED BY INHALATION EXPOSURE TO THIS PRODUCT.

First Aid:CALL POISON CENTER OR MD IMMED!DO NOT WAIT FOR SYMPTS.
EYES:IMMED FLUSH EYES W/LGE AMNTS OF WATER FOR AT LEAST 15 MINUTES
W/LIDS APART TO ENSURE RINSING OF ENTIRE SURF.SKIN:IMMED WIPE AWAY
EXCESS MATL W/DRY CLOTH.REMOVE ALL CONTAM CLOTHING& SHOES.FLUSH
THOROUGHLY FOR AT LEAST 15 MIN UNDER DELUGE SHOWER.INGEST:DO NOT
INDUCE VOM.MATL IS CORR.IMMED GIVE SEVERAL GLASSES OF WATER.KEEP
HEAD (SUPP DATA)

Flash Point:NONE
Extinguishing Media:DO NOT USE WATER. USE DRY CHEMICALS, CO2 SODA ASH
OR LIME.
Fire Fighting Procedures:IF NOT LEAKING,KEEP FIRE-EXPOS CNTNRS COOL
W/WATER SPRAY TO PRVNT RUPTURE DUE TO EXCESS HEAT.WEAR NIOSH/MSHA
APPRVD SCBA & FULL PROT EQUIP .
Unusual Fire/Explosion Hazard:DO NOT GET WATER IN CNTRS AS VIG REACTION
MAY RESULT.NOT FLAM/COMBUST,BUT MAY SUPPORT COMBUST & DECOMPOSE TO
GIVE OFF TOXIC MATLS.CONTAM BLDGS/AREAS/ (ING 3)

Spill Release Procedures:SWEEP SPILLED MATERIAL BEING CAREFUL NOT TO
CREATE DUST. PLACE IN CHEM WASTE CNTNR. COVER CONTAM AREA W/A
SLURRY OF COMMON HOUSEHOLD LAUNDRY DETERGENT & WATER.USE STIFF
BRUSH TO WORK SLURRY INTO CRACK S/CREVICES.ALLOW TO STND 2-3 MIN
THEN (SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CNTNRS SHOULD BE STORED IN COOL, DRY,
WELL- VENT AREA AWAY FROM FLAMMABLE MATERIALS AND SOURCES OF
HEAT/FLAME.STORE AWAY FROM FOOD STUFFS/ANIM FEED.
Other Precautions:EAT/DRINK/SMOKE SHLD BE PROHIB IN AREAS WHERE POTNTL
FOR EXPOS.EXERCISE DUE CAUTION TO PRVNT DAMG TO/LEAK FROM
CNTNR.NONCORR TO MATLS COMMON IN SHIP/STOR CNTNRS IF UNDER INERT
ATM.CONT W/MOISTURE LIBE RATES HCL WHICH WILL CORRODE MOST METALS

Respiratory Protection:NIOSH/MSHA APPROVED ACID-GAS RESP WITH DUST,
MIST, FUME FILTERS OR NIOSH/MSHA POSITIVE PRESSURE SCBA.
Ventilation:ENCLOSED SYSTEM IN COMBINATION W/LOCAL EXHAUST.
Protective Gloves:IMPERVIOUS GLOVES
Eye Protection:CHEMICAL WORKERS GOGGLES
Other Protective Equipment:IMPERVIOUS CLOTHING INCLUDING BOOTS SO NO
SKIN IS EXPOSED. SAFETY SHOWERS, EMERG EYE WASH FOUNTAINS.
Work Hygienic Practices:THOROUGHLY WASH HANDS/FACE BEFORE EATING.ALL
FOOD/TOBACCO SHLD BE KEPT IN AREA SEPARATE FROM MATERIAL.
Supplemental Safety and Health
FIRST AID PROC:BELOW HIPS IN CASE OF VOM. NEVER GIVE ANYTHING BY MOUTH
TO PERS UNCON/CONVULSG.CALL MD.INHAL:REMOVE TO FRESH AIR.IF NOT
BRTH ADMIN ARTF RESP.SUPP W/O2.KEEP PERS WARM & AT REST. SEVRE EX
POS MAY RSLT IN PNEUMONIA/PULM EDEMA.SPILL PROC:FLUSH W/WATER.DIKE
WATER FOR LATER DISPOSAL.DO NOT ALLOW CONTAM (ING 2)

HCC:C2
Solubility in Water:SOLUBLE
Appearance and Odor:PURPLE POWDER

Stability Indicator/Materials to Avoid:YES
PROD IS POWERFUL CHEM REDUCING AGENT IN PRESENCE OF OXIDIZERS.AVOID
MOISTURE, OXIDIZERS,METALS.
Stability Condition to Avoid:WILL RAPIDLY HYDROLYZE IN PRESENCE OF
MOISTURE RELEASING HAZ GAS & SUFF HEAT TO IGNITE OTHER MATL.STORE
UNDER INERT ATM.
Hazardous Decomposition Products:HLC GAS, TITANIUM OXIDES. HLC FUMES
MAY REACT W/METALS RELEASING FLAM/EXPLO HYDROGEN GAS.

Waste Disposal Methods:MATL THAT CANNOT BE USED OR CHEM REPROCESSED &
EMPTY CNTNRS SHOULD BE DISPOSED OF AT AN APPROVED FACILTIY IN
ACCORDANCE W/ ANY APPLICABLE FED,STATE & LOCAL REGULATIONS. NOTE:
STATE AND LOCAL REGULATIO NS MAY BE MORE STRINGENT THAN FEDERAL
REGULATIONS.

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